2024
147. Photochemical Organocatalytic Synthesis of Thioethers from Aryl Chlorides and Alcohols
W. Shuo, T. Hin-Fung Wong, P. Righi , & P. Melchiorre J. Am. Chem. Soc. 2024, DOI: 10.1021/jacs.3c13900 |
2023
146. Reductive Cross-Coupling of Olefins via a Radical Pathway
W. Zhuo, I. A. Dmitriev, & P. Melchiorre J. Am. Chem. Soc. 2023, 145, 25098-25102 |
145. A General Light-Driven Organocatalytic Platform for the Activation of Inert Substrates
W. Shuo, F. Schiel, & P. Melchiorre Angew. Chem.Int. Ed. 2023, 62, e202306364 ([Link]) |
144. Enantioselective catalytic remote perfluoroalkylation of a-branched enals driven by light
M. Balletti, T. Wachsmuth, A. Di Sabato, W. C. Hartley, & P. Melchiorre Chem. Sci. 2023, 14, 4923-4927 ([Link]) |
142. Photochemical Organocatalytic Functionalization of Pyridines via
Pyridinyl Radicals E. Le Saux, E. Georgiou, I. A. Dmitriev, W. C. Hartley, and P. Melchiorre J. Am. Chem. Soc. 2023, 145, 47–52 |
2022
141. Enantioselective Biocascade Catalysis with a Single Multifunctional Enzyme
V. Tseliou, A. Faraone, L. Kqiku, J. Vilim, G. Simionato and P. Melchiorre Angew. Chem. Int. Ed. 2022, e202212176 |
140. Enantioselective Tetrachlorophthalimides as Organocatalytic Acceptors for Electron Donor-Acceptor Complex Photoactivation
W. Zhou, S. Wu and P. Melchiorre J. Am. Chem. Soc. 2022, 144, 8914–8919 |
139. Switchable photocatalysis for the chemodivergent benzylation of 4-cyanopyridines
Eleni Georgiou, Davide Spinnato, Kang Chen, Paolo Melchiorre and Kilian Muñiz Chemical Science 2022, 13, 8060–8064 |
138. Lewis Base-Catalysed Enantioselective Radical Conjugate Addition for the Synthesis of Enantioenriched Pyrrolidinones
Will C. Hartley, Florian Schiel, Elena Ermini, and Paolo Melchiorre Angew. Chem. Int. Ed. 2022, 61, e202204735 |
137. Photochemical organocatalytic enantioselective radical γ-functionalization
of α-branched enals Matteo Balletti, Enrico Marcantonio, and Paolo Melchiorre Chem. Commun. 2022, 58, 6072-6075 |
135. Photochemical Organocatalytic Benzylation of Allylic C–H Bonds
Emilien Le Saux, Margherita Zanini, and Paolo Melchiorre J. Am. Chem. Soc. 2022, 144, 1113–1118 |
134. Introduction: Photochemical Catalytic Processes
Paolo Melchiorre Chem. Rev. 2022, 122, 1483–1484 Introduction to the Photochemical Catalytic Processes special issue |
133. Photoredox Organocatalysis for the EnantioselectiveSynthesis
of 1,7-Dicarbonyl Compounds Thomas Hin-Fung Wong, Dengke Ma, Riccardo Di Sanza, and Paolo Melchiorre Org. Lett. 2022, 24, 1695–1699 |
2021
132. Photochemical Organocatalytic Regio- and Enantioselective Conjugate Addition of Allyl Groups to Enals
Berger, M.; Carboni, D.; Melchiorre, P.
GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2021, 60, 1-6, DOI: 10.1002/anie.202111648.
Berger, M.; Carboni, D.; Melchiorre, P.
GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2021, 60, 1-6, DOI: 10.1002/anie.202111648.
131. A General Organocatalytic System for Electron Donor−Acceptor Complex Photoactivation and Its Use in Radical Processes
de Pedro Beato, E.; Spinnato, D.; Zhou, W.; Melchiorre, P.
GO TO OPEN ACCESS J. Am. Chem. Soc. 2021, 143, 12304-12314, DOI: 10.1021/jacs.1c05607.
*Among the top 20 most-read articles from the previous 30 days in JACS
de Pedro Beato, E.; Spinnato, D.; Zhou, W.; Melchiorre, P.
GO TO OPEN ACCESS J. Am. Chem. Soc. 2021, 143, 12304-12314, DOI: 10.1021/jacs.1c05607.
*Among the top 20 most-read articles from the previous 30 days in JACS
130. Catalytic asymmetric C–C cross-couplings enabled by photoexcitation
Crisenza, G. E. M.; Faraone, A.; Gandolfo, E.; Mazzarella, D.; Melchiorre, P.
Nat. Chem. 2021, 13, 575–580, DOI: 10.1038/s41557-021-00683-5.
*Read the paper here *Highlighted in Synfacts
Crisenza, G. E. M.; Faraone, A.; Gandolfo, E.; Mazzarella, D.; Melchiorre, P.
Nat. Chem. 2021, 13, 575–580, DOI: 10.1038/s41557-021-00683-5.
*Read the paper here *Highlighted in Synfacts
129. Photochemical Chemoselective Alkylation of Tryptophan-Containing Peptides
Laroche, B.; Tang, X.; Archer, G.; Di Sanza, R.; Melchiorre, P.
Org. Lett. 2021, 23 (2), 285–289, DOI: 10.1021/acs.orglett.0c03735.
*Among the top 3 recently published most-read articles for January in Organic Letters
Laroche, B.; Tang, X.; Archer, G.; Di Sanza, R.; Melchiorre, P.
Org. Lett. 2021, 23 (2), 285–289, DOI: 10.1021/acs.orglett.0c03735.
*Among the top 3 recently published most-read articles for January in Organic Letters
128. A General Organocatalytic System for Enantioselective Radical Conjugate Additions to Enals
Le Saux, E.; Ma, D.; Bonilla, P.; Holden, C.; Lustosa, D.; Melchiorre, P.
GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2021, 60 (10), 5357-5362, DOI: 10.1002/anie.202014876.
Le Saux, E.; Ma, D.; Bonilla, P.; Holden, C.; Lustosa, D.; Melchiorre, P.
GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2021, 60 (10), 5357-5362, DOI: 10.1002/anie.202014876.
2020
127. Photochemical generation of acyl and carbamoyl radicals using a nucleophilic organic catalyst: applications and mechanism thereof
de Pedro Beato, E.; Mazzarella, D.; Balletti, M; Melchiorre, P.
GO TO OPEN ACCESS Chem. Sci. 2020, 11, 6312–6324, DOI: 10.1039/D0SC02313B.
de Pedro Beato, E.; Mazzarella, D.; Balletti, M; Melchiorre, P.
GO TO OPEN ACCESS Chem. Sci. 2020, 11, 6312–6324, DOI: 10.1039/D0SC02313B.
126. Synthetic Methods Driven by the Photoactivity of Electron-Donor Acceptor Complexes
Crisenza, G. E. M.; Mazzarella, D.; Melchiorre, P.
GO TO OPEN ACCESS J. Am. Chem. Soc. 2020, 142 (12), 5461-5476, DOI: 10.1021/jacs.0c01416.
Crisenza, G. E. M.; Mazzarella, D.; Melchiorre, P.
GO TO OPEN ACCESS J. Am. Chem. Soc. 2020, 142 (12), 5461-5476, DOI: 10.1021/jacs.0c01416.
125. A Photochemical Organocatalytic Strategy for the α‐Alkylation of Ketones using Radicals
Spinnato, D.; Schweitzer-Chaput, B.; Goti, G.; Ošeka, M.; Melchiorre, P.
GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2020, 59, 9485–9490, DOI: 10.1002/anie.201915814.
* Highlighted on Synfacts
Spinnato, D.; Schweitzer-Chaput, B.; Goti, G.; Ošeka, M.; Melchiorre, P.
GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2020, 59, 9485–9490, DOI: 10.1002/anie.201915814.
* Highlighted on Synfacts
124. Amide Synthesis by Nickel/Photoredox‐Catalyzed Direct Carbamoylation of (Hetero)Aryl Bromides
Alandini, N.; Buzzetti, L.; Favi, G.; Schulte, T.; Candish, L.; Collins, K.; Melchiorre, P.
GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2020, 59 (13), 5248-5253, DOI: 10.1002/anie.202000224.
Alandini, N.; Buzzetti, L.; Favi, G.; Schulte, T.; Candish, L.; Collins, K.; Melchiorre, P.
GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2020, 59 (13), 5248-5253, DOI: 10.1002/anie.202000224.
123. Chemistry glows green with photoredox catalysis
Crisenza, G. E. M.; Melchiorre, P.
GO TO OPEN ACCESS Nat. Commun. 2020, 11, 803, DOI: 10.1038/s41467-019-13887-8.
Crisenza, G. E. M.; Melchiorre, P.
GO TO OPEN ACCESS Nat. Commun. 2020, 11, 803, DOI: 10.1038/s41467-019-13887-8.
2019
122. Photo‐Organocatalytic Enantioselective Radical Cascade Enabled by Single‐Electron Transfer Activation of Allenes
Alessandro-Perego, L.; Bonilla, P.; Melchiorre P.
Adv. Synth. Catal. 2019, 362 (2), 302-307, DOI: 10.1002/adsc.201900973.
* Among the top 10% most downloaded papers in Advanced Synthesis & Catalysis in the 12 months following online publication.
Alessandro-Perego, L.; Bonilla, P.; Melchiorre P.
Adv. Synth. Catal. 2019, 362 (2), 302-307, DOI: 10.1002/adsc.201900973.
* Among the top 10% most downloaded papers in Advanced Synthesis & Catalysis in the 12 months following online publication.
121. Photochemistry and excited-state reactivity of organocatalytic intermediates
Holden, C. M.; Melchiorre, P.
BOOK CHAPTER In: "Photochemistry: Volume 47", Royal Society of Chemistry, 2019, 344 - 378, (ISBN: 978-1-78801-554-7)DOI: 10.1039/9781788016520-00344.
Holden, C. M.; Melchiorre, P.
BOOK CHAPTER In: "Photochemistry: Volume 47", Royal Society of Chemistry, 2019, 344 - 378, (ISBN: 978-1-78801-554-7)DOI: 10.1039/9781788016520-00344.
120. Photochemical C‐H Hydroxyalkylation of Quinolines and Isoquinolines
Bieszczad, B.; Alessandro Perego, L.; Melchiorre, P.
GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2019, 58 (47), 16878-16883, DOI: 10.1002/anie.201910641.
* Among the top 10% most downloaded papers in Angewandte Chemie International Edition in the 12 months following online publication.
Bieszczad, B.; Alessandro Perego, L.; Melchiorre, P.
GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2019, 58 (47), 16878-16883, DOI: 10.1002/anie.201910641.
* Among the top 10% most downloaded papers in Angewandte Chemie International Edition in the 12 months following online publication.
119. Photochemical Asymmetric Nickel‐Catalyzed Acyl Cross‐Coupling
Gandolfo, E.; Tang, X.; Raha Roy, S.; Melchiorre, P.
GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2019, 58 (47), 16854-16858, DOI: 10.1002/anie.201910168.
* Among the top 10% most downloaded papers in Angewandte Chemie International Edition in the 12 months following online publication.
Gandolfo, E.; Tang, X.; Raha Roy, S.; Melchiorre, P.
GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2019, 58 (47), 16854-16858, DOI: 10.1002/anie.201910168.
* Among the top 10% most downloaded papers in Angewandte Chemie International Edition in the 12 months following online publication.
118. Photochemical Organocatalytic Borylation of Alkyl Chlorides, Bromides, and Sulfonates
Mazzarella, D.; Magagnano, G.; Schweitzer-Chaput, B.; Melchiorre, P.
GO TO OPEN ACCESS ACS Catal. 2019, 9, 5876-5880, DOI: 10.1021/acscatal.9b01482.
* Among the most read ACS Catal. articles in 2019
** Among the Top 20 most downloaded articles for the previous 12 months
*** Highlighted by Synfacts
Mazzarella, D.; Magagnano, G.; Schweitzer-Chaput, B.; Melchiorre, P.
GO TO OPEN ACCESS ACS Catal. 2019, 9, 5876-5880, DOI: 10.1021/acscatal.9b01482.
* Among the most read ACS Catal. articles in 2019
** Among the Top 20 most downloaded articles for the previous 12 months
*** Highlighted by Synfacts
117. A visible-light mediated three-component radical process using dithiocarbamate anion catalysis
Cuadros, S.; Horwitz, M. A.; Schweitzer-Chaput, B.; Melchiorre, P.
GO TO OPEN ACCESS Chem. Sci. 2019, 10, 5484–5488, DOI: 10.1039/C9SC00833K.
Cuadros, S.; Horwitz, M. A.; Schweitzer-Chaput, B.; Melchiorre, P.
GO TO OPEN ACCESS Chem. Sci. 2019, 10, 5484–5488, DOI: 10.1039/C9SC00833K.
116. Mechanistic Studies in Photocatalysis
Buzzetti, L.; Crisenza, G. E. M.; Melchiorre, P.
COVER GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2019, 58 (12), 3730-3747, DOI: 10.1002/anie.201809984.
Buzzetti, L.; Crisenza, G. E. M.; Melchiorre, P.
COVER GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2019, 58 (12), 3730-3747, DOI: 10.1002/anie.201809984.
115. A Redox Active Nickel Complex that Acts as an Electron Mediator in Photochemical Giese Reactions
van Leeuwen, T.; Buzzetti, L.; Alessandro Perego, L.; Melchiorre, P.
GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2019, 58 (15), 4953-4957, DOI: 10.1002/anie.201814497.
*Highlighted in Synfacts
* Among the top 10% most downloaded papers in Angewandte Chemie International Edition in the 12 months following online publication.
van Leeuwen, T.; Buzzetti, L.; Alessandro Perego, L.; Melchiorre, P.
GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2019, 58 (15), 4953-4957, DOI: 10.1002/anie.201814497.
*Highlighted in Synfacts
* Among the top 10% most downloaded papers in Angewandte Chemie International Edition in the 12 months following online publication.
114. Stereocontrolled Synthesis of 1,4‐Dicarbonyl Compounds by Photochemical Organocatalytic Acyl Radical Addition to Enals
Goti, G.; Bieszczad, B.; Vega-Peñaloza, A.; Melchiorre, P.
GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2019, 58, 1213-1217, DOI: 10.1002/anie.201810798.
Goti, G.; Bieszczad, B.; Vega-Peñaloza, A.; Melchiorre, P.
GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2019, 58, 1213-1217, DOI: 10.1002/anie.201810798.
113. Photochemical generation of radicals from alkyl electrophiles using a nucleophilic organic catalyst
Schweitzer-Chaput, B.; Horwitz, M. A.; de Pedro Beato, E.; Melchiorre, P.
GO TO OPEN ACCESS Nat. Chem. 2019, 11, 129–135, DOI: 10.1038/s41557-018-0173-x.
*** Highlighted by SYNFORM
Schweitzer-Chaput, B.; Horwitz, M. A.; de Pedro Beato, E.; Melchiorre, P.
GO TO OPEN ACCESS Nat. Chem. 2019, 11, 129–135, DOI: 10.1038/s41557-018-0173-x.
*** Highlighted by SYNFORM
2018
112. Organocatalysis with Amines in Photocatalysis
Y. P. Rey, H. B. Hepburn, P. Melchiorre
BOOK CHAPTER In: "Science of Synthesis: Photocatalysis in Organic Synthesis", Thieme, 2018, 1, 243, (ISBN: 9783132417021)DOI: 10.1055/sos-SD-229-00133.
Y. P. Rey, H. B. Hepburn, P. Melchiorre
BOOK CHAPTER In: "Science of Synthesis: Photocatalysis in Organic Synthesis", Thieme, 2018, 1, 243, (ISBN: 9783132417021)DOI: 10.1055/sos-SD-229-00133.
111. Photo‐Organocatalytic Enantioselective Radical Cascade Reactions of Unactivated Olefins
P. Bonilla, Y. Rey, C. Holden, P. Melchiorre
GO TO OPEN ACCESS Angew. Chem. Int. Ed 2018, 57, 12819-12823, DOI: 10.1002/anie.201808183.
*Highlighted in Synfacts
* Among the top 10% most downloaded papers in Angewandte Chemie International Edition in the 12 months following online publication.
P. Bonilla, Y. Rey, C. Holden, P. Melchiorre
GO TO OPEN ACCESS Angew. Chem. Int. Ed 2018, 57, 12819-12823, DOI: 10.1002/anie.201808183.
*Highlighted in Synfacts
* Among the top 10% most downloaded papers in Angewandte Chemie International Edition in the 12 months following online publication.
110. Enantioselective radical conjugate additions driven by a photoactive intramolecular iminium-ion-based EDA complex
Z. Cao, T. Ghosh, P. Melchiorre
GO TO OPEN ACCESS Nat. Commun. 2018, 9 (3274), DOI: 10.1038/s41467-018-05375-2.
Z. Cao, T. Ghosh, P. Melchiorre
GO TO OPEN ACCESS Nat. Commun. 2018, 9 (3274), DOI: 10.1038/s41467-018-05375-2.
109. Asymmetric Photocatalytic C–H Functionalization of Toluene and Derivatives
D. Mazzarella, G.E.M. Crisenza, P. Melchiorre
GO TO OPEN ACCESS J. Am. Chem. Soc. 2018, 140 (27), 8439–8443, DOI: 10.1021/JACS.8B05240.
*Highlighted in Synfacts
D. Mazzarella, G.E.M. Crisenza, P. Melchiorre
GO TO OPEN ACCESS J. Am. Chem. Soc. 2018, 140 (27), 8439–8443, DOI: 10.1021/JACS.8B05240.
*Highlighted in Synfacts
108. Organocatalytic Strategies to Stereoselectively Trap Photochemically Generated Hydroxy-o-quinodimethanes
S. Cuadros, P. Melchiorre
Eur. J. Org. Chem. 2018, 2884-2891, DOI: 10.1002/ejoc.201800081.
S. Cuadros, P. Melchiorre
Eur. J. Org. Chem. 2018, 2884-2891, DOI: 10.1002/ejoc.201800081.
107. Enhancing the potential of enantioselective organocatalysis with light
M. Silvi, P. Melchiorre
GO TO OPEN ACCESS Nature 2018, 554, 41-49, DOI: 10.1038/nature25175.
M. Silvi, P. Melchiorre
GO TO OPEN ACCESS Nature 2018, 554, 41-49, DOI: 10.1038/nature25175.
106. Enantioselective Photochemical Organocascade Catalysis
L. Woźniak, G. Magagnano, P. Melchiorre
GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2018, 57, 1068-1072, DOI: 10.1002/anie.201711397.
L. Woźniak, G. Magagnano, P. Melchiorre
GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2018, 57, 1068-1072, DOI: 10.1002/anie.201711397.
105. Direct Stereoselective Installation of Alkyl Fragments at the β-Carbon of Enals via Excited Iminium Ion Catalysis
C. Verrier, N. Alandini, C. Pezzetta, M. Moliterno, L. Buzzetti, H.B. Hepburn, A. Vega-Peñaloza, M. Silvi, P. Melchiorre
ACS Catal. 2018, 8 (2), 1062-1066, DOI: 10.1021/acscatal.7b03788.
* Among the most cited articles in January 2018
C. Verrier, N. Alandini, C. Pezzetta, M. Moliterno, L. Buzzetti, H.B. Hepburn, A. Vega-Peñaloza, M. Silvi, P. Melchiorre
ACS Catal. 2018, 8 (2), 1062-1066, DOI: 10.1021/acscatal.7b03788.
* Among the most cited articles in January 2018
2017
104. Radical-based C-C Bond-Forming Processes Enabled by the Photoexcitation of 4-Alkyl-1,4-dihydropyridines
L. Buzzetti, A. Prieto, S.R. Roy, P. Melchiorre
GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2017, 56 (47), 15039-15043 , DOI: 10.1002/anie.201709571.
L. Buzzetti, A. Prieto, S.R. Roy, P. Melchiorre
GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2017, 56 (47), 15039-15043 , DOI: 10.1002/anie.201709571.
103. Forging Quaternary Fluorine Stereocenters by a Light-driven Organocatalytic Aldol Desymmetrization Process
S. Cuadros, L. Dell'Amico, P. Melchiorre
GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2017, 56 (39), 11875-11879 , DOI: 10.1002/anie.201706763.
* Highlighted in Synfacts 2017, 13, 1086 (DOI: 10.1055/s-0036-1591221).
S. Cuadros, L. Dell'Amico, P. Melchiorre
GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2017, 56 (39), 11875-11879 , DOI: 10.1002/anie.201706763.
* Highlighted in Synfacts 2017, 13, 1086 (DOI: 10.1055/s-0036-1591221).
102. Enantioselective Formal α-Methylation and α-Benzylation of Aldehydes by Means of Photo-Organocatalysis
G. Filippini, M. Silvi, P. Melchiorre
GO TO OPEN ACCESS Angew. Chem., Intl. Ed. 2017, 56, 4447-4451, DOI: 10.1002/anie.201612045.
G. Filippini, M. Silvi, P. Melchiorre
GO TO OPEN ACCESS Angew. Chem., Intl. Ed. 2017, 56, 4447-4451, DOI: 10.1002/anie.201612045.
101. Visible-light excitation of iminium ions enables the enantioselective catalytic β-alkylation of enals
M. Silvi, C. Verrier, Y.P. Rey, L. Buzzetti, P. Melchiorre.
GO TO OPEN ACCESS Nat. Chem. 2017, DOI: 10.1038/nchem.2748.
*Highlighted in Chemistry World
**Previewed in Chem, 2017, 2, 616-618 (DOI: 10.1016/j.chempr.2017.04.020).
M. Silvi, C. Verrier, Y.P. Rey, L. Buzzetti, P. Melchiorre.
GO TO OPEN ACCESS Nat. Chem. 2017, DOI: 10.1038/nchem.2748.
*Highlighted in Chemistry World
**Previewed in Chem, 2017, 2, 616-618 (DOI: 10.1016/j.chempr.2017.04.020).
100. Studies on the Enantioselective Iminium Ion Trapping of Radicals Triggered by an Electron-Relay Mechanism
A. Bahamonde, J.J. Murphy, M. Savarese, E. Bremond, A. Cavalli, P. Melchiorre
GO TO OPEN ACCESS J. Am. Chem. Soc. 2017, 139, 4559-4567, DOI: 10.1021/jacs.7b01446.
A. Bahamonde, J.J. Murphy, M. Savarese, E. Bremond, A. Cavalli, P. Melchiorre
GO TO OPEN ACCESS J. Am. Chem. Soc. 2017, 139, 4559-4567, DOI: 10.1021/jacs.7b01446.
99. Light-Driven Enantioselective Organocatalytic β-Benzylation of Enals
L. Dell'Amico, V.M. Fernández-Álvarez, F. Maseras, P. Melchiorre
GO TO OPEN ACCESS Angew. Chem., Intl. Ed. 2017, 56, 3304-3308, DOI: 10.1002/anie.201612159.
*Among most accessed in February 2017.
L. Dell'Amico, V.M. Fernández-Álvarez, F. Maseras, P. Melchiorre
GO TO OPEN ACCESS Angew. Chem., Intl. Ed. 2017, 56, 3304-3308, DOI: 10.1002/anie.201612159.
*Among most accessed in February 2017.
98. Light-triggered Enantio selective Organocatalytic Mannich-type Reaction
H.B. Hepburn, G. Magagnano, P. Melchiorre
Synthesis 2017, 49 (1), 76-86, DOI: 10.1055/s-0036-1588606.
Special Issue celebrating the 70th birthday of Prof. Dr. Dieter Enders (Invited paper)
H.B. Hepburn, G. Magagnano, P. Melchiorre
Synthesis 2017, 49 (1), 76-86, DOI: 10.1055/s-0036-1588606.
Special Issue celebrating the 70th birthday of Prof. Dr. Dieter Enders (Invited paper)
2016
97. Mechanism of the Stereoselective α-Alkylation of Aldehydes Driven by the Photochemical Activity of Enamines
A. Bahamonde, P. Melchiorre
GO TO OPEN ACCESS J. Am. Chem. Soc. 2016, 138, 8019-8030.
A. Bahamonde, P. Melchiorre
GO TO OPEN ACCESS J. Am. Chem. Soc. 2016, 138, 8019-8030.
96. Enantioselective Vinylogous Organocascade Reactions
H. B. Hepburn, L. Dell'Amico, P. Melchiorre
The Chemical Record 2016, In press DOI: 10.1002/tcr.201600030.
H. B. Hepburn, L. Dell'Amico, P. Melchiorre
The Chemical Record 2016, In press DOI: 10.1002/tcr.201600030.
95. Asymmetric catalytic formation of quaternary carbons by iminium ion trapping of radicals
J. J. Murphy, D. Bastida, S. Paria, M. Fagnoni, P. Melchiorre
Nature 2016, 532, 218-222.
* Highlighted in Synfacts, 2016, 12 (07), 739 and Chemical and Engineering News 2016, 94 (16), 9.
J. J. Murphy, D. Bastida, S. Paria, M. Fagnoni, P. Melchiorre
Nature 2016, 532, 218-222.
* Highlighted in Synfacts, 2016, 12 (07), 739 and Chemical and Engineering News 2016, 94 (16), 9.
94. Enantioselective Organocatalytic Diels–Alder Trapping of Photochemically Generated Hydroxy-o-Quinodimethanes
L. Dell'Amico, A. Vega-Peñaloza, S. Cuadros, P. Melchiorre
GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2016, 55, 3313-3317.
L. Dell'Amico, A. Vega-Peñaloza, S. Cuadros, P. Melchiorre
GO TO OPEN ACCESS Angew. Chem. Int. Ed. 2016, 55, 3313-3317.
93. Brønsted acid-catalysed conjugate addition of photochemically generated α-amino radicals to alkenylpyridines
H. B. Hepburn, P. Melchiorre
GO TO OPEN ACCESS Chem. Commun. 2016, 52, 3520-3523.
H. B. Hepburn, P. Melchiorre
GO TO OPEN ACCESS Chem. Commun. 2016, 52, 3520-3523.
2015
92. Organic chemistry: Light opens pathways for nickel catalysis
J. J. Murphy, P. Melchiorre
Nature 2015, 524, 297-298.
* News & views section of the journal.
This is a comment on a paper published in the same issue of Nature (p. 330)
J. J. Murphy, P. Melchiorre
Nature 2015, 524, 297-298.
* News & views section of the journal.
This is a comment on a paper published in the same issue of Nature (p. 330)
91. Photochemical direct perfluoroalkylation of phenols
G. Filippini, M. Nappi, P. Melchiorre
Tetrahedron 2015, 71, 4535-4542.
G. Filippini, M. Nappi, P. Melchiorre
Tetrahedron 2015, 71, 4535-4542.
90. Computational Study with DFT and Kinetic Models on the Mechanism of Photoinitiated Aromatic Perfluoroalkylations
V. M. Fernández-Álvarez, M. Nappi, P. Melchiorre, F. Maseras
Org. Lett. 2015, 17, 2676-2679.
V. M. Fernández-Álvarez, M. Nappi, P. Melchiorre, F. Maseras
Org. Lett. 2015, 17, 2676-2679.
89. Diastereodivergent organocatalysis for the asymmetric synthesis of chiral annulated furans
C. Verrier, P. Melchiorre
GO TO OPEN ACCESS Chem. Sci. 2015, 6, 4242-4246.
C. Verrier, P. Melchiorre
GO TO OPEN ACCESS Chem. Sci. 2015, 6, 4242-4246.
88. Enantioselective Organocatalytic Alkylation of Aldehydes and Enals Driven by the Direct Photoexcitation of Enamines
M. Silvi, E. Arceo, I. D. Jurberg, C. Cassani, P. Melchiorre
GO TO OPEN ACCESS J. Am. Chem. Soc. 2015, 137, 6120-6123.
*Highlighted in Synfacts 2015, issue 7, 765
M. Silvi, E. Arceo, I. D. Jurberg, C. Cassani, P. Melchiorre
GO TO OPEN ACCESS J. Am. Chem. Soc. 2015, 137, 6120-6123.
*Highlighted in Synfacts 2015, issue 7, 765
87. Photo-organocatalytic Enantioselective Perfluoroalkylation of β-Ketoesters
Ł. Woźniak, J. J. Murphy, P. Melchiorre
GO TO OPEN ACCESS J. Am. Chem. Soc. 2015, 137, 5678-5681.
*Among the JACS Top 20 most downloaded articles over the last 12 months
Ł. Woźniak, J. J. Murphy, P. Melchiorre
GO TO OPEN ACCESS J. Am. Chem. Soc. 2015, 137, 5678-5681.
*Among the JACS Top 20 most downloaded articles over the last 12 months
86. X-Ray Characterization of an Electron Donor-Acceptor Complex that Drives the Photochemical Alkylation of Indoles
S. R. Kandukuri, A. Bahamonde, I. Chatterjee, I. D. Jurberg, E. C. Escudero-Adán, P. Melchiorre
Angew. Chem. Int. Ed. 2015, 54, 1485-1489.
S. R. Kandukuri, A. Bahamonde, I. Chatterjee, I. D. Jurberg, E. C. Escudero-Adán, P. Melchiorre
Angew. Chem. Int. Ed. 2015, 54, 1485-1489.
2014
85. Photo-Organocatalysis of Atom-Transfer Radical Additions to Alkenes
E. Arceo, E. Montroni, P. Melchiorre
Angew. Chem. Int. Ed. 2014, 53, 12064-12068.
*Highlighted in ChemistryViews
*Highlighted in Synfacts 2014, issue 12, 1325
*Highlighted in ChemCatChem, 2015, 7, 735
*Among the ACIE most accessed in Sept/2014
E. Arceo, E. Montroni, P. Melchiorre
Angew. Chem. Int. Ed. 2014, 53, 12064-12068.
*Highlighted in ChemistryViews
*Highlighted in Synfacts 2014, issue 12, 1325
*Highlighted in ChemCatChem, 2015, 7, 735
*Among the ACIE most accessed in Sept/2014
84. Metal-Free Photochemical Aromatic Perfluoroalkylation of α-Cyano Arylacetates
M. Nappi, G. Bergonzini, P. Melchiorre
Angew. Chem. Int. Ed. 2014, 53, 4921-4925.
*Selected as HOT Paper
*Highlighted in Synform, issue 2014/09
M. Nappi, G. Bergonzini, P. Melchiorre
Angew. Chem. Int. Ed. 2014, 53, 4921-4925.
*Selected as HOT Paper
*Highlighted in Synform, issue 2014/09
83. Asymmetric Vinylogous Diels–Alder Reactions Catalyzed by a Chiral Phosphoric Acid
X. Tian, N. Hofmann, P. Melchiorre
Angew. Chem. Int. Ed. 2014, 53, 2997-3000.
*Highlighted in Synfacts 2014, issue 04, 433
X. Tian, N. Hofmann, P. Melchiorre
Angew. Chem. Int. Ed. 2014, 53, 2997-3000.
*Highlighted in Synfacts 2014, issue 04, 433
82. Enantioselective direct α-alkylation of cyclic ketones by means of photo-organocatalysis
E. Arceo, A. Bahamonde, G. Bergonzini, P. Melchiorre
Chem. Sci. 2014, 5, 2438-2442.
*Highlighted in Synfacts, 2014, issue 5, 535
E. Arceo, A. Bahamonde, G. Bergonzini, P. Melchiorre
Chem. Sci. 2014, 5, 2438-2442.
*Highlighted in Synfacts, 2014, issue 5, 535
81. Synthesis of Cyclopropane Spirooxindoles by means of a Vinylogous Organocatalytic Cascade
R. César da Silva, I. Chatterjee, E. Escudero-Adán, M. Weber Paixao, P. Melchiorre
Asian J. Org. Chem. 2014, 3, 466-469.
R. César da Silva, I. Chatterjee, E. Escudero-Adán, M. Weber Paixao, P. Melchiorre
Asian J. Org. Chem. 2014, 3, 466-469.
2013
80. Controlling the Molecular Topology of Vinylogous Iminium Ions by Logical Substrate Design: Highly Regio- and Stereoselective Aminocatalytic 1,6-Addition to Linear 2,4-Dienals
M. Silvi, I. Chatterjee, Y. Liu, P. Melchiorre
Angew. Chem. Int. Ed. 2013, 52, 10780-10783.
M. Silvi, I. Chatterjee, Y. Liu, P. Melchiorre
Angew. Chem. Int. Ed. 2013, 52, 10780-10783.
79. Vinylogous Organocatalytic Triple Cascade Reaction: Forging Six Stereocenters in Complex Spiro-Oxindolic Cyclohexanes
I. Chatterjee, D. Bastida, P. Melchiorre
Adv. Synth. Catal. 2013, 355, 3124-3130.
I. Chatterjee, D. Bastida, P. Melchiorre
Adv. Synth. Catal. 2013, 355, 3124-3130.
78. Photochemical activity of a key donor–acceptor complex can drive stereoselective catalytic α-alkylation of aldehydes
E. Arceo, I.D. Jurberg, A. Álvarez-Fernández, P. Melchiorre
Nat. Chem. 2013, 5, 750-756.
*Highlighted in Synfacts 2013, issue 11, 1229
E. Arceo, I.D. Jurberg, A. Álvarez-Fernández, P. Melchiorre
Nat. Chem. 2013, 5, 750-756.
*Highlighted in Synfacts 2013, issue 11, 1229
77. A Mechanistic Rationale for the 9-Amino(9-deoxy)epi Cinchona Alkaloids Catalyzed Asymmetric Reactions via Iminium Ion Activation of Enones
A. Moran, A. Hamilton, C. Bo, P. Melchiorre, Paolo
J. Am. Chem. Soc. 2013, 135, 9091-9098.
*Highlighted in Synfacts 2013, issue 08, 891
A. Moran, A. Hamilton, C. Bo, P. Melchiorre, Paolo
J. Am. Chem. Soc. 2013, 135, 9091-9098.
*Highlighted in Synfacts 2013, issue 08, 891
76. Control of Remote Stereochemistry in the Synthesis of Spirocyclic Oxindoles: Vinylogous Organocascade Catalysis
X. Tian, P. Melchiorre
Angew. Chem. Int. Ed. 2013, 52, 5360-5363.
X. Tian, P. Melchiorre
Angew. Chem. Int. Ed. 2013, 52, 5360-5363.
75. When asymmetric aminocatalysis meets the vinylogy principle
I.D. Jurberg, I. Chatterjee, R. Tannert, P. Melchiorre
Chem. Commun. 2013, 49, 4869-4883.
I.D. Jurberg, I. Chatterjee, R. Tannert, P. Melchiorre
Chem. Commun. 2013, 49, 4869-4883.
74. Synthesis of 9-amino(9-deoxy)epi cinchona alkaloids, general chiral organocatalysts for the stereoselective functionalization of carbonyl compounds
C. Cassani, R. Martín-Rapún, E. Arceo, F. Bravo, P. Melchiorre
Nat. Protoc. 2013, 8, 325-344.
C. Cassani, R. Martín-Rapún, E. Arceo, F. Bravo, P. Melchiorre
Nat. Protoc. 2013, 8, 325-344.
73. Asymmetric vinylogous aldol reaction via H‑Bond-directing dienamine catalysis
D. Bastida, Y. Liu, X. Tian, E. Escudero-Adán, P. Melchiorre
Org. Lett. 2013, 15, 220-223.
D. Bastida, Y. Liu, X. Tian, E. Escudero-Adán, P. Melchiorre
Org. Lett. 2013, 15, 220-223.
2012
72. Direct catalytic enantioselective vinylogous Aldol reaction of alpha-branched enals with isatins
C. Cassani, P. Melchiorre
Org. Lett. 2012, 14, 5590-5593.
C. Cassani, P. Melchiorre
Org. Lett. 2012, 14, 5590-5593.
71. Secondary amine-catalyzed asymmetric gamma-alkylation of alpha-branched enals via dienamine activation
M. Silvi, C. Cassani, A. Moran, P. Melchiorre
Helvetica Chim. Acta 2012, 95, 1985-2006.
M. Silvi, C. Cassani, A. Moran, P. Melchiorre
Helvetica Chim. Acta 2012, 95, 1985-2006.
70. Cinchona-based primary amine catalysis in the asymmetric functionalization of carbonyl compounds
P. Melchiorre
Angew. Chem. Int. Ed. 2012, 51, 9748-9770.
P. Melchiorre
Angew. Chem. Int. Ed. 2012, 51, 9748-9770.
69. Aminocatalytic enantioselective 1,6 additions of alkyl thiols to cyclic dienones: Vinylogous iminium ion activation
X. Tian, Y. Liu, P. Melchiorre
Angew. Chem. Int. Ed. 2012, 51, 6439-6442.
Highlighted in Synfact 2012, 905
X. Tian, Y. Liu, P. Melchiorre
Angew. Chem. Int. Ed. 2012, 51, 6439-6442.
Highlighted in Synfact 2012, 905
68. Extending the aminocatalytic HOMO-raising activation strategy: Where is the limit?
E. Arceo, P. Melchiorre
Angew. Chem. Int. Ed. 2012, 51, 5290-5292.
E. Arceo, P. Melchiorre
Angew. Chem. Int. Ed. 2012, 51, 5290-5292.
67. A bio-inspired route to alpha-amino acid derivatives
E. Arceo, P. Melchiorre
ChemCatChem 2012, 4, 459-461.
E. Arceo, P. Melchiorre
ChemCatChem 2012, 4, 459-461.
66. Multicatalytic asymmetric synthesis of complex tetrahydrocarbazoles via a Diels-Alder/benzoin reaction sequence
Y. Liu, M. Nappi, E. C. Escudero-Adán, P. Melchiorre
Org. Lett. 2012, 14, 1310-1313.
Y. Liu, M. Nappi, E. C. Escudero-Adán, P. Melchiorre
Org. Lett. 2012, 14, 1310-1313.
65. Dioxindole in asymmetric catalytic synthesis: direct access to 3-substituted 3-hydroxy-2-oxindoles via 1,4-additions to nitroalkenes
M. Retini, G. Bergonzini, P. Melchiorre
Chem. Commun. 2012, 48, 3336-3338.
M. Retini, G. Bergonzini, P. Melchiorre
Chem. Commun. 2012, 48, 3336-3338.
64. Dioxindole in asymmetric catalytic synthesis: Routes to enantioenriched 3-substituted 3-hydroxyoxindoles and the preparation of Maremycin A
G. Bergonzini, P. Melchiorre
Angew. Chem. Int. Ed. 2012, 51, 971-974.
Highlighted in Synfact 2012, 329
G. Bergonzini, P. Melchiorre
Angew. Chem. Int. Ed. 2012, 51, 971-974.
Highlighted in Synfact 2012, 329
2011
63. Diastereodivergent asymmetric sulfa-Michael additions of alpha-branched enones using a single chiral organic catalyst
X. Tian, C. Cassani, Y. Liu, A. Moran, A. Urakawa, P. Galzerano, E. Arceo, P. Melchiorre
J. Am. Chem. Soc. 2011, 133, 17934-17941.
Highlighted in Science 2011, 334, 570 & in Synfact 2012, 213
X. Tian, C. Cassani, Y. Liu, A. Moran, A. Urakawa, P. Galzerano, E. Arceo, P. Melchiorre
J. Am. Chem. Soc. 2011, 133, 17934-17941.
Highlighted in Science 2011, 334, 570 & in Synfact 2012, 213
62. Asymmetric catalysis of Diels-Alder reactions with in situ generated heterocyclic ortho-quinodimethanes
Y. Liu, M. Nappi, E. Arceo, S. Vera, Paolo Melchiorre
J. Am. Chem. Soc. 2011, 133, 15212-15218.
Y. Liu, M. Nappi, E. Arceo, S. Vera, Paolo Melchiorre
J. Am. Chem. Soc. 2011, 133, 15212-15218.
61. Asymmetric Michael addition of nitrobenzyl pyridines to enals via iminium catalysis
S. Vera, Y. Liu, M. Marigo, E. C. Escudero-Adán, P. Melchiorre
Synlett 2011, 489-494.
S. Vera, Y. Liu, M. Marigo, E. C. Escudero-Adán, P. Melchiorre
Synlett 2011, 489-494.
60. Multiple approaches to enantiopure spirocyclic benzofuranones using organocatalytic cascade reactions
C. Cassani, X. Tian, E. C. Escudero-Adán, P. Melchiorre
Chem. Commun. 2011, 47, 233-235.
C. Cassani, X. Tian, E. C. Escudero-Adán, P. Melchiorre
Chem. Commun. 2011, 47, 233-235.
2010
59. Perchloric acid and its salts: Very powerful catalysts in organic chemistry
R. Dalpozzo, G. Bartoli, L. Sambri, P. Melchiorre
Chem. Rev. 2010, 110, 3501-3551.
R. Dalpozzo, G. Bartoli, L. Sambri, P. Melchiorre
Chem. Rev. 2010, 110, 3501-3551.
58. Cinchona alkaloids in synthesis & catalysis
P. Melchiorre
Angew. Chem. Int. Ed. 2010, 49, 3259-3260 (Comment of book).
P. Melchiorre
Angew. Chem. Int. Ed. 2010, 49, 3259-3260 (Comment of book).
57. Cooperative organocatalysis for the asymmetric γ-alkylation of α-branched enals
G. Bergonzini, S. Vera, P. Melchiorre
Angew. Chem. Int. Ed. 2010, 49, 9685-9688.
Highlighted in Synfact 2011, 101
G. Bergonzini, S. Vera, P. Melchiorre
Angew. Chem. Int. Ed. 2010, 49, 9685-9688.
Highlighted in Synfact 2011, 101
56. Direct asymmetric vinylogous Michael addition of cyclic enones to nitroalkenes via dienamine catalysis
G. Bencivennia, P. Galzeranoa, A. Mazzantia, G. Bartolia, P. Melchiorre
Proc. Natl. Acad. Sci. U.S.A. 2010, 107, 20642-20647.
Organocatalysis Special Issue – Highlighted in Synfact 2010, 1299 and Selected as Synfact of the Month
G. Bencivennia, P. Galzeranoa, A. Mazzantia, G. Bartolia, P. Melchiorre
Proc. Natl. Acad. Sci. U.S.A. 2010, 107, 20642-20647.
Organocatalysis Special Issue – Highlighted in Synfact 2010, 1299 and Selected as Synfact of the Month
55. Asymmetric catalytic aziridination of cyclic enones
F. De Vincentiis, G. Bencivenni, F. Pesciaioli, A. Mazzanti, G. Bartoli, P. Galzerano, P. Melchiorre
Chem. Asian J. 2010, 5, 1652-1656.
F. De Vincentiis, G. Bencivenni, F. Pesciaioli, A. Mazzanti, G. Bartoli, P. Galzerano, P. Melchiorre
Chem. Asian J. 2010, 5, 1652-1656.
54. Organocatalytic asymmetric conjugate additions of oxindoles and benzofuranones to cyclic enones
F. Pesciaioli, X. Tian, G. Bencivenni, G. Bartoli, P. Melchiorre
Synlett 2010, 11, 1704-1708.
F. Pesciaioli, X. Tian, G. Bencivenni, G. Bartoli, P. Melchiorre
Synlett 2010, 11, 1704-1708.
53. Chemoselectivity in asymmetric aminocatalysis
M. Marigo, P. Melchiorre
ChemCatChem 2010, 2, 621-623.
M. Marigo, P. Melchiorre
ChemCatChem 2010, 2, 621-623.
52. Controlling stereoselectivity in the aminocatalytic enantioselective Mannich reaction of aldehydes with in situ generated N-carbamoyl imines
P. Galzerano, D. Agostino, G. Bencivenni, L. Sambri, G. Bartoli, P. Melchiorre
Chem. Eur. J. 2010, 16, 6069-6076.
P. Galzerano, D. Agostino, G. Bencivenni, L. Sambri, G. Bartoli, P. Melchiorre
Chem. Eur. J. 2010, 16, 6069-6076.
2009
51. Asymmetric organocatalytic cascade reactions with α-substituted α,β-unsaturated aldehydes
P. Galzerano, F. Pesciaioli, A. Mazzanti, G. Bartoli, P. Melchiorre
Angew. Chem. Int. Ed. 2009, 48, 7892-7894.
Highlighted in Synfact 2009, 1278
P. Galzerano, F. Pesciaioli, A. Mazzanti, G. Bartoli, P. Melchiorre
Angew. Chem. Int. Ed. 2009, 48, 7892-7894.
Highlighted in Synfact 2009, 1278
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